After the kerfuffle, below, about a picture identified by the library as St. Anthony but which appears to be St. Joseph's, in Maumee, I decided to run this one. It's identified as St. Francis de Sales.
UPDATE: Kevin Hammer pointed out, by noticing a sign at the upper left, that the picture's reversed. Mystery solved. It's the old St. Paul's Methodist, which was torn down in 1914.